1: Sounds like a bright child (3).
 2: Alternative to following performance needed when a substitution is required. (5)
 3: A country, one said, in trouble (9)
 4: Concealed hot part of psyche (3)
 5: Put a new value on what secret agent is hiding (5)
 8: Scheme conclusion for jet set (5)
 9: Freeze one mug filled with tea, essentially (3,2)
 11: Backblock not all there (3)
 13: Sister gets nothing, we hear (3)